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Keep salt away
from the rebars.
Do not allow
the protective iron oxide to move away from the steel.
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SDC
Consortium Makes Life-365 Available
Model Predicts Service Life of Concrete Structure in
Salt Environment |
Low Permeability Concrete
with a Corrosion Inhibitor Will Virtually Eliminate Corrosion ProblemsKnowing the service life of a concrete structure allows the engineer to
build cost effectively. The Strategic Develop-ment Council of ACI recognized the need for
a consensus model to do this. A consortium under SDC funded this development and now the
first generation of the model, Life-365, is available through those companies and
organizations that sponsored the work. CCIA will be one of the organizations that sponsor
a second consortium to improve the model and develop the necessary data for its future
use.
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| Methods
to Control Corrosion In Concrete |
Concrete, itself, is one of the best
protective coatings for steel. Reinforced Concrete gains its strength from the strong bond
between the steel reinforc-ing and the concrete. If the bond is lost the concrete
properties are diminished. When salt is allowed to penetrate concrete, the corrosion
protection properties of concrete are lost (see below). Salt gets into concrete when the
roads are salted in the winter and when concrete structures are built along the seacoast.
Also, some aggregates and admixtures contain salt. Concrete can also loose its protective
quality in heavy industrial environments where CO2 gets into the concrete and
reduces the pH.
One
of the best ways to control corrosion, when chloride or carbon dioxide penetrate, is to
add a corrosion inhibitor while making the concrete. Corrosion inhibitors work with
concrete to maintain the protection without the loss of bond.
However, when a
corrosion inhibitor is used, the concrete quality must be maintained the same as without
the inhibitor. There are other ways to reduce the probability of corrosion that should be
considered along with the use of a corrosion inhibitor. The most important of which is to
reduce the permeability of the concrete. Lower permeability reduces the amount of salt
that can get into the concrete and, of course, this lessens the problem. The permeability
can be reduced by the use of a water reducing agent or/and the use of selected pozzolans,
such as certain fly ashes, granulated blast furnace slag, blended cement or condensed
silica fume. Ensuring that there is at least two inches of concrete cover over the rebars
does not reduce the permeability but it does make it more difficult for the salt to get to
the steel in the concrete.
If the concrete is
kept dry it is difficult for the salt to get in, but this is practically impossible to do.
However, curing concrete well reduces the permeability and improves the strength. Thus,
careful attention to curing is important.
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| Steel in
Concrete Corrodes by a Different Mechanism |
If you have ever seen an old iron gate or a
ships anchor that has been left outdoors, you know that it is usually covered with
different colored layers of rust. Unlike aluminum, which reacts with oxygen to form one
oxide coating that protects it from further corrosion, iron forms at least three different
iron oxides (i.e., hematite, magnetite, and limonite), which can change from one form to
the other depending on temperature and humidity. These layers of oxides have different
dimensions, so that the changes expose fresh surfaces of iron to further corrosion. In
concrete when salt is present, a soluble iron complex forms with the salt. This complex
can move away from the rebar, exposing fresh surfaces and allowing corrosion to continue.
A corrosion inhibitor stops the complex formation and allows only one coating to form on
iron as in the case of aluminum. |
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